Films and getters · Workhorse
Boron and lithium wall conditioning
Bvalues describe: boronisation
Why it wins
Sacrificial gettering films (boronization by diborane, lithium evaporation) buy oxygen pumping and low recycling that a tungsten wall no longer provides for free.
Why not the alternative
Permanent getters cannot survive plasma contact: the consumable film is the design.
Watch out
An operations discipline, not a component: chemistry per campaign.
Properties
The values below are candidate: compiled from the sources named, not yet individually validated. Provisional provenance: ITER and JET ITER-like wall programme; EUROfusion and international fusion materials programmes.
Wet cleaning
| Recipe | not applicable: the wall is conditioned in situ by glow discharge or evaporation, not washed |
|---|---|
| Forbidden | the whole point is that you cannot open the machine to clean it |
| Limit | campaign length, and the tritium inventory the film retains |
Vacuum and outgassing
| Outgassing, unbaked (10 h) | pumps hydrogen and oxygen |
|---|---|
| Vapour pressure | lithium evaporates readily, which is the mechanism |
Temperature
| Bake, assembled | in-vessel, machine dependent |
|---|---|
| Metallurgical limit | the film is consumed and reapplied each campaign |
Thermal
| Melting / softening | 2076 (B) °C |
|---|
Mechanical
| Strength | film |
|---|---|
| Elongation | nil |
| Density | 2.34 g/cm3 |
Electrical and magnetic
| Relative permeability | 1.0 |
|---|
Engineering
| Joining | deposited on the whole inner wall |
|---|---|
| Process notes | a consumable surface, renewed between campaigns |
| Availability and cost | tokamak practice |
Grades
| Diborane diluted in He, glow discharge | the ITER-class boronization consumable |
|---|---|
| Li evaporation | low recycling campaigns, spherical tokamak and stellarator practice |
| B powder injection (impurity powder dropper) | real-time boronization without glow discharge: DIII-D, ASDEX-U, EAST practice |